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Swarts reaction : ウィキペディア英語版
Antimony trifluoride

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Antimony trifluoride is the inorganic compound with the formula SbF3. Sometimes called Swart's reagent, is one of two principal fluorides of antimony, the other being SbF5. It appears as a white solid. As well as some industrial applications,〔Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. 〕 it is used as a reagent in inorganic and organofluorine chemistry.ncert india class 12 vol.2 chapter1
==Preparation and structure==
In solid SbF3, the Sb centres have octahedral molecular geometry and are linked by bridging fluoride ligands. Three Sb–F bonds are short (192 pm) and three are long (261 pm). Because it is a polymer, SbF3 is far less volatile than related compounds AsF3 and SbCl3.
SbF3 is prepared by treating antimony trioxide with hydrogen fluoride:〔Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 199.〕
:Sb2O3 + 6 HF → 2 SbF3 + 3 H2O
The compound is a mild Lewis acid, hydrolyzing slowly in water. With fluorine, it is oxidized to give antimony pentafluoride.
:SbF3 + F2 → SbF5

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